OK, so even though I have been burning DVDs in Toast from the "Clapper" tab > VIDEO_TS folders for at least 5 years...
Someone CHANGED the process to:
If you have DVD data that is already authored in a Video_TS folder, here are the steps you should use to burn it to DVD:
1) Launch Toast and select the "Data" tab.
2) In the drawer, select "Advanced" at the top.
3) Select the "DVD-ROM (UDF)" format.
4) Click on the "New Disc" button at the bottom of the layout.
5) Use the "Add" button to select your Video_TS folder, or drag and drop the folder into your layout.
6) Now you can add additional data content or burn the disc.
Dragging the same VIDEO_TS folder this way does NOT produce the CSS copying error. After it successfully burned a new DVD, I clicked on the Clapper tab again, and sure enough, got the CSS Can't Copy error on the same VIDEO_TS folder!!
Using this new method almost is the same as the previous, except that it does not automatically name the disc based on the Folder name that the VIDEO_TS folder is enclosed in. The default is now "My_Disc", or you can type/paste into a text input box.